中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Resonance Raman spectroscopic and density functional theory study of p-nitroacetophenone (PNAP)
作者: Pei, Kemei;  Ma, Yufang;  Zheng, Xuming;  Li, Haiyang
通讯作者: Xuming Zheng ;  李海洋
刊名: CHEMICAL PHYSICS LETTERS
发表日期: 2007-03-22
DOI: 10.1016/j.cplett.2007.02.013
卷: 437, 期:1-3, 页:153-158
收录类别: SCI
文章类型: Article
部门归属: 1
项目归属: 102
产权排名: 2;4
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: Resonance Raman spectra of p-nitroacetophenone(PNAP) have been obtained in resonance with the charge-transfer (CT) band using 252.7, 266 and 273.9 nm in methanol solvent. The spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the C=O stretching v(8)(1691 cm(-1)) and the benzene ring stretch v(10)(1593 cm(-1)). A preliminary resonance Raman intensity analysis was done and the results for PNAP were compared with nitrobenzene and aceptophenone. Our results indicate that -NO2 is more photoactive than -COCH3. The isomerization process of PNAP takes place somewhere after the wave packet leaves the Franck-Condon region. (c) 2007 Elsevier B.V. All rights reserved.
关键词[WOS]: TIME PHOTODISSOCIATION DYNAMICS ;  A-BAND ABSORPTION ;  NITRO-COMPOUNDS ;  CYCLOHEXANE SOLUTION ;  BACTERIAL-SPORES ;  MLCT TRANSITION ;  TRIPLET-STATE ;  BIOTRANSFORMATION ;  SENSITIZATION ;  REDUCTION
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000245401200030
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/99843
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Zhejiang Univ, Minist Educ, Key Lab Adv Text Mat & Mfg Technol, Hangzhou 310018, Peoples R China

Recommended Citation:
Pei, Kemei,Ma, Yufang,Zheng, Xuming,et al. Resonance Raman spectroscopic and density functional theory study of p-nitroacetophenone (PNAP)[J]. CHEMICAL PHYSICS LETTERS,2007,437(1-3):153-158.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Pei, Kemei]'s Articles
 [Ma, Yufang]'s Articles
 [Zheng, Xuming]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Pei, Kemei]‘s Articles
 [Ma, Yufang]‘s Articles
 [Zheng, Xuming]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace