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Resonance Raman spectroscopy and density functional theory study of the photodissociation dynamics of acetophenone in cyclohexane solution
Ma, Yufang1,2; Pei, Kemei1,2; Zheng, Xuming1,2; Li, Haiyang3; Xuming Zheng; Li HY(李海洋); Xuming Zheng; Li HY(李海洋)
刊名CHEMICAL PHYSICS LETTERS
2007-11-26
DOI10.1016/j.cplett.2007.10.044
449期:1-3页:107-114
收录类别SCI
文章类型Article
部门归属1
项目归属102
产权排名2;4
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]PI-PI-ASTERISK ; RELAXATION DYNAMICS ; ABSORPTION-SPECTRA ; CARBONYL-COMPOUNDS ; ELECTRONIC STATES ; BAND ABSORPTION ; EXCITED-STATES ; TRIPLET-STATES ; BENZALDEHYDE ; SUBSTITUENTS
英文摘要Resonance Raman spectra were acquired for acetophenone using 228.7, 239.5, and 245.9 nm excitations in cyclohexane solution. The spectra display overtones of the benzene ring C - C stretch (1578 cm(-1)) and the carbonyl C=O stretch (1671 cm(-1)) modes and their combination bands with other five vibrational modes. A preliminary resonance Raman intensity analysis was done and these results for acetophenone were compared to the those previously reported for 2-hydroxyacetophenone. The differences between the vibrational reorganizational energies for acetophenone relative to those of 2-hydroxyacetophenone were briefly discussed. (c) 2007 Elsevier B.V. All rights reserved.
语种英语
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WOS记录号WOS:000251575300021
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/99845
专题中国科学院大连化学物理研究所
通讯作者Xuming Zheng; Li HY(李海洋); Xuming Zheng; Li HY(李海洋)
作者单位1.Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Peoples R China
2.Zhejiang Sci Tech Univ, Key Lab ATMMT, MOE, Hangzhou 310018, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Ma, Yufang,Pei, Kemei,Zheng, Xuming,et al. Resonance Raman spectroscopy and density functional theory study of the photodissociation dynamics of acetophenone in cyclohexane solution[J]. CHEMICAL PHYSICS LETTERS,2007,449(1-3):107-114.
APA Ma, Yufang.,Pei, Kemei.,Zheng, Xuming.,Li, Haiyang.,Xuming Zheng.,...&李海洋.(2007).Resonance Raman spectroscopy and density functional theory study of the photodissociation dynamics of acetophenone in cyclohexane solution.CHEMICAL PHYSICS LETTERS,449(1-3),107-114.
MLA Ma, Yufang,et al."Resonance Raman spectroscopy and density functional theory study of the photodissociation dynamics of acetophenone in cyclohexane solution".CHEMICAL PHYSICS LETTERS 449.1-3(2007):107-114.
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