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题名: Electron transfer theory revisited: Quantum solvation effect
作者: Han, Ping;  Xu, Rui-Xue;  Cui, Ping;  Mo, Yan;  He, Guczhong;  Yan, Yijing
通讯作者: 严以京
关键词: electron transfer ;  quantum solvation ;  quantum dissipation
刊名: JOURNAL OF THEORETICAL & COMPUTATIONAL CHEMISTRY
发表日期: 2006-09-01
卷: 5, 期:3, 页:685-692
收录类别: SCI
文章类型: Article
部门归属: 11
项目归属: 1101
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The effect of solvation on ET rate processes has been investigated on the basis of the exact theory constructed in J. Phys. Chem. B 110:11438, 2006. The nature of solvation has been studied in close relation with the mechanism of ET processes. The resulting Kramers' turnover and Marcus' inversion characteristics have been analyzed accordingly. The classical picture of solvation has been found to be invalid when the solvent longitudinal relaxation time is short compared with the inverse temperature.
关键词[WOS]: DIELECTRIC FRICTION ;  LIOUVILLE-SPACE ;  POLAR-SOLVENTS ;  DEBYE SOLVENTS ;  DYNAMICS ;  BIOMOLECULES ;  TRANSITION ;  KINETICS ;  MOTION ;  MODEL
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000241507200013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/99891
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
3.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

Recommended Citation:
Han, Ping,Xu, Rui-Xue,Cui, Ping,et al. Electron transfer theory revisited: Quantum solvation effect[J]. JOURNAL OF THEORETICAL & COMPUTATIONAL CHEMISTRY,2006,5(3):685-692.
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